C_(60)及富勒烯族化合物的研究代表了当前新理论和新材料研究的新潮流.自从1990年Kr(?)tschmer等人利用电弧法获得宏观量C_(60)以来,C_(60)的研究已取得了重大进展.人们通过各种各样的化学反应方法,将许许多多功能不同的取代基引入到C_(60)球体结构中,合成了一系列C_(60)有机衍生物.C_(60)分子的足球状微观结构决定其固体微粒具有较高的耐压强度,作为碳元素的一种单质,C_(60)本身可以作为火箭推进剂的添加剂.如果能给C_(60)分子中引入多硝基苯基等含能基团,将会得到一种新型的笼状含能材料添加物.本文通过硝基苯类叠氮化与 The study of C_ (60) and fullerenes represents a new trend in the research of new theories and new materials. Since Kr (?) Tschmer et al obtained the macroscopic C_ (60) by arc method in 1990, C_ ) Has made great progress.A variety of chemical reactions have been used to introduce many kinds of functional substituents into the C 60 spherical structure and a series of C 60 organic derivatives have been synthesized The C_ (60) molecular football microstructure determines that the solid particles have high compressive strength. As a single element of carbon, C_ (60) itself can be used as an additive for rocket propellant. ) Molecules into the functional groups such as polynitrophenyl, will get a new type of cage-like material additives.In this paper, nitrobenzene azide and