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The title coordination polymer, [Co(1,4-ndc)(L)(H2O)]n 1 (1,4-H2ndc = 1,4-na-phthalenedicarboxylic acid and L = 1-(5-(1H-imidazol-1-yl)pentyl)-1H-imidazole) has been hydrothermally synthesized and characterized by IR and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P21/n with a = 12.4333(12), b = 13.2963(13), c = 13.4678(13) , α = β = 90°, γ =107.302(2)°, V = 2125.7(4) 3, Z = 4, CoC22H22N4O5, Mr = 481.37, Dc = 1.504 g/cm3, F(000) = 996, μ(MoKa) = 0.850 mm-1, R = 0.0472 and wR = 0.0984. Compound 1 exhibits a two-dimensional layer structure. The O-H···O and C-H···O hydrogen bonds stabilize the structure of 1.
The title coordination polymer, [Co (1,4-ndc) (L) (H2O)] n 1 (1,4-H2ndc = 1,4-na-phthalenedicarboxylic acid and L = 1- -1-yl) pentyl) -1H-imidazole) has been hydrothermally synthesized and characterized by IR and single-crystal X-ray diffraction. It crystallizes in monoclinic space group P21 / n with a = 12.4333 (12), b = Α = β = 90 °, γ = 107.302 (2) °, V = 2125.7 (4) 3, Z = 4, CoC22H22N4O5, Mr = 481.37, Dc = 1.504 g / cm 3, F (000) = 996, μ (MoKa) = 0.850 mm -1, R = 0.0472 and wR = 0.0984. The OH ··· O and CH ··· O hydrogen bond stabilize the structure of 1.