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本工作设计和合成了十个由夹心型金属有机化合物阳离子与金属二硫醇配合物[M(mnt)_2]阴离子组成的金属有机盐类化合物:(M’Cp_2)[M(mnt)_2]或[FeCp(Tol)]_n[M(mnt)_2],其中M=Ni,Pd,Co,Cu或Zn;M’=Fe或Co;Gp代表环戊二烯基;Tol代表甲苯;mnt代表;n=1或2).通过元素分析、IR和NMR对化合物进行表征,测定了[FeCp(Tol)]_2[Ni(mnt)_2]的单晶结构.Mossbauer谱和ESR表明(FeCp_2)[Ni(mnt)_2]是个混合价化合物,提出了该化合物的生成反应机理.测定了所有化合物的固体电导率和部分化合物的固体磁学性质.
This work designed and synthesized ten metal organic salts composed of sandwich metal-organic compound cation and metal dithiol complex [M (mnt) _2] anions: (M’Cp_2) [M (mnt) _2] Wherein M = Ni, Pd, Co, Cu or Zn; M ’= Fe or Co; Gp represents cyclopentadienyl; Tol represents toluene; mnt represents ; n = 1 or 2. The single crystal structure of [FeCp (Tol)] _2 [Ni (mnt) _2] has been characterized by elemental analysis, IR and NMR.The Mossbauer spectra and ESR show that (FeCp_2) Ni (mnt) _2] is a mixed valence compound, and the formation reaction mechanism of the compound is proposed. The solid conductivity and the solid magnetic properties of all the compounds were measured.