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四氮杂大环配合物是生物体内一些金属酶结构单元的模拟物,可作为振荡反应催化剂来加以研究.我们报道的一些四氮杂大环铜(Ⅱ)、镍(Ⅱ)配合物所参与的催化振荡反应体系中采用的底液都是稀H_2SO_4,尚未见以H_3PO_4作底液的报道。然而研究以H_3PO_4作底液的
Tetraaza macrocyclic complexes are mimics of some metalloenzyme structural units in vivo and can be used as oscillating reaction catalysts.We reported that some tetraazacyclized copper (II) and nickel (II) complexes participated in Of the catalytic oscillation reaction system used in the bottom liquid are dilute H_2SO_4, H_3PO_4 has not been seen as the end of the liquid reported. However, the study of H_3PO_4 as the bottom of the liquid