一般含有P~(111)-NR_2结构的磷化合物能与胺类化合物发生氨基交换反应。本文报道化合物2-苯基-3-N,N-二烷基氨基苯并噻唑并[2,3-d]2,3-二氢-1,2,4,3-三唑磷茂啉(1a,1b)与胺类化合物进行氨基交换反应的结果。la或1b与仲胺反应可顺利进行得产物lc-lj,其中1c-ld为已知化合物,其余六个化合物均未见文献报道。 Phosphorus compounds generally containing P ~ (111) -NR 2 structure can undergo amino exchange reaction with amine compounds. The compound 2-phenyl-3-N, N-dialkylaminobenzothiazolo [2,3-d] 2,3-dihydro- 1, 2,4,3- triazophosphorolan ( 1a, 1b) as a result of the amino group exchange reaction with the amine compound. Lc or 1b and secondary amine reaction can be smoothly carried out the product lc-lj, which 1c-ld known compounds, the remaining six compounds were not reported in the literature.