论文部分内容阅读
标题配合物 [Cu(C8H4 F3O2 S) 2 (C12 H8N2 ) ]·C3H6 O属于三斜晶系 ,空间群为P1,并测得如下晶胞参数a =10 .5 77(3) ,b =15 .72 2 (4) ,c =10 .133(2 ) ,α =94 .5 3(2 ) ,β =10 0 .81(2 ) ,γ =96 .18(2 )° ,V =16 37.0 3 3,Z =2 ,Mr =74 4.18,Dx =1.5 1× 10 6 g·m- 3,F(0 0 0 ) =5 2 6 ,μ =8 2 4cm- 1,最终偏差因子为R =0 .0 83,Rw=0 .0 74。Cu(II)与 2个 4 ,4 ,4 三氟 1 (2 噻吩基 )丁二酮 1,3中的四个氧原子和菲咯啉中的两个氮原子 ,组成了一个畸变的八面体构型。
The title complex [Cu (C8H4F3O2S) 2 (C12H8N2)] C3H6O belongs to the triclinic system with space group P1 and the following unit cell parameters a = 10 .577 (3), b = 15 .72 2 (4), c = 10 .133 (2), α = 94.53 (2), β = 100.81 (2), γ = 96.18 (2) °, V = 16 37.0 3, Z = 2, Mr = 74 4.18, Dx = 1.5 1 × 10 6 g · m -3, F 0 0 0 = 5 2 6, μ = 8 2 4cm -1, the final deviation factor is R = 0 .0 83, Rw = 0 .0 74. Four oxygen atoms in Cu (II) and two 4, 4, 4 trifluoro 1 (2-thienyl) butanedione 1,3 and two nitrogen atoms in phenanthroline make up a distorted octahedron structure.