综述了近年来钛族配合物在有机合成中应用的新进展。包括高立体选择性和化学选择性进行催化氢化、还原、开环、环化、酰胺化，催化下格氏试剂与不饱和七、八元杂环高立体选择性的加成反应，格氏试剂对环状烯丙醇进行选择性加氢，炔锆配合物高化学选择性、立体选择性与醛反应，Ｃｐ２Ｚｒ（Ｈ）Ｃｌ与烯、炔加成生成亲核试剂，Ｃｐ２ＺｒＣｌ２／ＭＡＯ（Ａｌ／Ｚｒ为１∶１）催化烯烃齐聚等。 Recent advances in the application of titanium family complexes in organic synthesis are reviewed. Including highly stereoselective and chemical selective catalytic hydrogenation, reduction, ring opening, cyclization, amidation, catalysis of Grignard reagent and unsaturated seven, eight yuan heterocyclic highly stereoselective addition reaction, Grignard reagent The selective hydrogenation of cyclic allylic alcohols, the acetylene zirconium complexes with high chemical selectivity, stereoselectivity and aldehyde reaction, the formation of nucleophilic reagents Cp2ZrCl2 / MAO (Al / Zr is 1: 1) to catalyze the oligomerization of olefins.