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在文[1、2]的基础上,建立了r=7的无量纲参数法,用该法研究了苯甲酸乙酯皂化、乙酸乙酯皂化、苄基氯与氢氧化钠反应的动力学.并对二级反应热动力学研究法的有关问题作了讨论.本文所用原理与实验方法在文[1—3]已作了介绍.
On the basis of [1] and [2], a dimensionless parameter method with r = 7 was established. The kinetics of saponification of ethyl benzoate, saponification of ethyl acetate and reaction of benzyl chloride with sodium hydroxide were studied by this method. And discussed the related problems of the secondary reaction thermokinetic method.The principles and experimental methods used in this paper have been introduced in [1-3].