On the role of ketone in the tribological behaviour of zinc dialkyldithiophosphate

来源 :Science in China,Ser.A | 被引量 : 0次 | 上传用户:aaronfly08
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This study reports the influence of methyl isopropyl ketone, which often kept in com-mercial zinc dialkyldithiophosphate (ZDDP) as a residue, on the tribological performance of ZDDP.The lubricity test of 500 SN neutral base stock oil containing ZDDP with methyl isopropyl ketonewas carried out by MQ--800 four-ball thbometer. The experimental results show that the methylisopropyl ketone results in the decrement of the wear resistance of ZDDP. The ketone compounddecreases greatly the load-carry capacity of ZDDP. The fact that the antiwear performance ofZDDP reduces with the addition of methyl isopropyl ketone could be partly attributed to a nucleo-philic substitution reaction, which retards the formation of phosphate antiwear films. This study reports the influence of methyl isopropyl ketone, which often kept in com-mer zinc lacquihidithiophosphate (ZDDP) as a residue, on the tribological performance of ZDDP. Lubricity test of 500 SN neutral base stock oil containing ZDDP with methyl isopropyl ketonewas carried The experimental results show that the methylisopropyl ketone results in the decrement of the wear resistance of ZDDP. The ketone compound decreases greatly the load-carry capacity of ZDDP. The fact that the antiwear performance of ZDDP reduces with the addition of methyl isopropyl ketone could be partly attributed to a nucleo-philic substitution reaction, which retards the formation of phosphate antiwear films.
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