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基团转移聚合(GTP)是Webster等首先发现的一种新型的聚合方法。最常用的引发剂为甲基三甲基硅烷基二甲乙烯酮缩醛(MTS)。催化剂有负离子型(如HF_2~-,CN~-等)和Lewis酸型。Bandermann和Mai研究了甲基丙烯酸甲酯(MMA)的负离子催化剂的GTP动学。Hertler和Sogah报道了Lewis酸催化剂的聚合反
Group transfer polymerization (GTP) is a novel aggregation method first discovered by Webster et al. The most commonly used initiator is methyl trimethylsilyldimethyl ketal (MTS). Catalysts are negative ions (such as HF_2 ~ -, CN ~ -) and Lewis acid type. Bandermann and Mai studied the GTP kinetics of anionic catalysts for methyl methacrylate (MMA). Hertler and Sogah reported the polymerization of Lewis acid catalysts