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本文用慢应变速率实验(SSRT)方法研究了奥氏体304不锈钢焊接接头在室温HCl+NaCl溶液中应力腐蚀开裂(SCC)敏感性H+浓度和Cl-浓度是影响该体系发生SCC的两个重要因素,H+浓度的改变可使材料的腐蚀形态发生变化,对SCC敏感的酸度范围为:5.0x10-4~30MH+,并给出体系“304不锈钢焊缝/HCl+NaCl”的应力腐蚀状态图([Cl-]-[H+]-SCC图)焊缝区是焊接接头的SCC敏感区,应力腐蚀裂纹是沿着被选择性溶解的奥氏体枝晶间的δ-铁素体扩展的,断口具有奥氏体枝晶骨架的形貌.该体系发生的是活化态下的应力腐蚀.
In this paper, we studied the sensitivity of stress corrosion cracking (SCC) to austenitic 304 stainless steel welded joint at room temperature in HCl + NaCl solution by using a slow strain rate test (SSRT) method. H + concentration and Cl- concentration are the two important factors affecting SCC. The change of H + concentration can change the corrosion morphology of the material. The sensitivity range of SCC is 5.0x10-4 ~ 30MH +, and the stress corrosion state of “304 stainless steel weld / HCl + NaCl” ] - [H +] - SCC) The weld zone is the SCC sensitive zone of the welded joint. The stress corrosion cracking propagates along the δ-ferrite between the selectively dissolved austenite dendrites. The fracture has the austenite Body dendrite skeleton morphology. The system is under stress corrosion in the activated state.