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在298.6K~318.2K温度范围内,研究了磁场对乙酸乙酯皂化反应速率常数的影响。结果表明,在磁场条件下,反应速率常数明显增大;反应的活化焓与活化熵分别降低11.86kJ·mol-1和34.33J·mol-1K-1。对磁场影响乙酸乙酯皂化反应速率的原因进行了分析讨论
The effect of magnetic field on the rate constant of ethyl acetate saponification reaction was studied in the temperature range of 298.6K ~ 318.2K. The results showed that the reaction rate constant increased significantly under magnetic field conditions. The activation enthalpy and activation entropy decreased by 11.86 kJ · mol-1 and 34.33 J · mol-1K-1, respectively. The reason of the influence of magnetic field on the rate of saponification of ethyl acetate was discussed and discussed