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合成了对叔丁基杯[4]芳烃，对叔丁基杯[6]芳烃及对叔丁基杯[4]芳烃的羟基氢被乙酸乙酯或乙酸甲酯取代的衍生物；进而在不同溶剂中合成了这些杯芳烃与碱金属钾、钠等离子所形成的四种未见报道的固体配合物，利用元素分析、红外先谱、核磁共振、等离子光谱等方法对其进行了表征，得出相应的固体配合物组成，还简要讨论了四种固体配合物的可能的形成机理和结构．
The derivatives of p-tert-butyl calix [4] arene, p-tert-butyl calix [6] arene and p-tert-butyl calix [4] arene were substituted with ethyl acetate or methyl acetate. Four unreported solid complexes of these calixarenes with alkaline potassium and sodium ions were synthesized in solvent and characterized by elemental analysis, infrared spectrum, nuclear magnetic resonance and plasma spectroscopy. The corresponding solid complex composition, also briefly discussed the possible formation mechanism and structure of the four solid complexes.