Oxidation Behaviors of C-ZrB_2-SiC Composite at 2100℃ in Air and O_2

来源 :Journal of Materials Science & Technology | 被引量 : 0次 | 上传用户:absyou
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The oxidation behaviors of graphite and ZrB_2-SiC modified graphite composite were investigated at 2100℃ in1X105 Pa air and 0.2X105 Pa O2. The oxidation tests were conducted in an induction heating furnace. The oxidation of these two materials followed the linear rate law. The determined radius loss rates of graphite and C-ZrB_2-Si C at 2100℃ were 2.18X10-2and 1.05X10-2%/s in 1X105 Pa air, and 3.23X10 2 and 2.21X10 2%/s in 0.2X105 Pa O2, respectively. The incorporation of ZrB2 and SiC decreased remarkably the oxidation rate of graphite because the oxide scale formed on the sample surface during oxidation helps in reducing the exposed surface area of the underneath substrate. In two different atmospheres with the same oxygen partial pressure, both graphite and ZrB_2-SiC experienced more severe oxidation at 2100℃ in0.2X105 Pa O2than in 1X105 Pa air. The oxidation rate-controlling step for graphite and ZrB_2-SiC was proposed to be the inward diffusion of oxygen through the boundary layer and through the pores in the oxide scale, respectively. A model based on diffusion theory was established to discuss the effect of the total gas pressure on their oxidation behaviors. The oxidation behaviors of graphite and ZrB_2-SiC modified graphite composite were investigated at 2100 ° C in 1 × 105 Pa air and 0.2 × 105 Pa O2. The oxidation tests were conducted in an induction heating furnace. The oxidation of these two materials followed the linear rate law. The determined radius loss rates of graphite and C-ZrB_2-Si C at 2100 ° C. were 2.18 × 10 -2 and 1.05 × 10 -2% / s in 1 × 10 5 Pa air and 3.23 × 10 2 and 2.21 × 10 2% / s in 0.2 × 10 5 Pa O 2, respectively. The incorporation of ZrB2 and SiC decreased remarkably the oxidation rate of graphite because the oxide scale formed on the sample surface during oxidation helps in reducing the exposed surface area of ​​the underneath substrate. both two atmospheres with the same oxygen partial pressure, both graphite and ZrB_2-SiC was more severe oxidation at 2100 ℃ in0.2X105 Pa O2than in 1X105 Pa air. The oxidation rate-controlling step for graphite and ZrB_2-SiC was proposed to be the inward diffusion of oxygen through the boundary layer and through the pores in the oxide scale, respectively. A model based on diffusion theory was established to discuss the effect of the total gas pressure on their oxidation behaviors.
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