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研究了3,5-二硝基水杨酸在pH=3.0的盐酸介质中的阴极波特性,其二阶导数还原峰电流Ip"(Ep"=—0.36VvsSCE)与浓度在5.0×10-8~1.0×10-5mol/L范围内具有良好的线性关系,RSD=0.55%(8次平行实验),检测限为1.8×10-8mol/L。通过循环伏安等方法证明3,5-二硝基水杨酸在汞电极上为一含吸附的受扩散控制的不可逆过程。此外,还研究了人体内常见微量物质及表面活性剂对Ip"的影响。
The cathode wave properties of 3,5-dinitrosalicylic acid in hydrochloric acid at pH = 3.0 were studied. The second derivative reduction peak current Ip “(Ep” = -0.36 VvsCE) There was a good linearity in the range of 0 × 10-8 ~ 1.0 × 10-5mol / L with RSD = 0.55% (eight parallel experiments) and the detection limit was 1.8 × 10-8mol / L. Cyclic voltammetry and other methods to prove 3,5 - dinitrosalicylic acid in the mercury electrode is an adsorption-controlled diffusion process irreversible process. In addition, also studied the human body common trace substances and surfactants on the impact of Ip ".