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用Ｘ射线光电子能谱（ＸＰＳ）研究了聚苯硫醚（ＰＰＳ）在高温下的化学反应和ＰＰＳ与不锈钢、铸铁、Ａ３碳钢的结合机理。结果表明，ＰＰＳ在３００℃以上发生了氧化交联和氧化反应，反应中有Ｃ－Ｏ－Ｃ、Ｐｈ－ＳＯ－Ｐｈ和Ｐｈ－ＳＯ２－Ｐｈ基团生成，涂层界面的Ｐｈ－Ｓ－Ｐｈ中的Ｓ有２３％生成了Ｐｈ－ＳＯ－Ｐｈ和Ｐｈ－ＳＯ２－Ｐｈ。同时初步解释了ＰＰＳ涂层与金属界面的结合是由于ＰＰＳ中Ｓ原子的孤对电子和金属基体的Ｆｅ３＋发生配位，生成具有一定数量的多核大分子配合物所致。
The chemical reaction of polyphenylene sulfide (PPS) at high temperature and the bonding mechanism of PPS with stainless steel, cast iron and A3 carbon steel were studied by X-ray photoelectron spectroscopy (XPS). The results showed that the oxidation-crosslinking and oxidation of PPS occurred at above 300 ℃. The reaction of C-O-C, Ph-SO-Ph and Ph-SO2-Ph groups occurred at the coating interface. 23% of S generated Ph-SO-Ph and Ph-SO2-Ph. At the same time, a preliminary explanation of the combination of the PPS coating with the metal interface is due to the coordination between the lone pair electrons of the S atom in the PPS and the Fe3 + metal matrix, resulting in a complex with a certain number of polynuclear macromolecules.