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利用溶胶-凝胶分配理论对氢键溶液的模型体系进行研究,给出了体系的凝胶化条件以及凝胶点后氢键网络中各类结构参数的计算方案,并进行了相应的数值计算.结果表明,当两类质子受体基团的活性不同时,质子受体基团的竞争作用对网络结构有一定影响.这为控制氢键网络结构特征提供了可能的理论线索.
The model system of hydrogen bonding solution was studied by using the sol-gel distribution theory. The gelation conditions of the system and the calculation schemes of various structural parameters in the hydrogen bonding network after the gel point were given. Corresponding numerical calculations The results show that the competition of proton acceptor group has an influence on the network structure when the activity of two kinds of proton acceptor groups is different, which provides the possible theoretical clues for controlling the structural characteristics of hydrogen bond network.