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A novel coordination ploymer [Cd(HO-BDC)(phen)·H2O]n (where HO-BDC is 5-Hydroxyisophthalic acid and phen is 1,10-phenanthroline) has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P2/c, with a=0.876 4(2) nm, b=1.233 0(3) nm, c=1.761 2(4) nm, β=109.152(9)°, V=1.797 8(7) nm3, Z=4, Mr=490.73, Dc=1.813 g·cm-3, F(000)=976, μ=1.258 mm-1, the final R=0.043 8 and wR=0.098 9 for 2 880 observed reflections with I>2σ(I). The structural analysis shows that the complex has a one-dimensional chain structure. CCDC: 609770.
A novel coordination ploymer [Cd (HO-BDC) (phen) · H2O] n (where HO-BDC is 5-Hydroxyisophthalic acid and phen is 1,10-phenanthroline) has been synthesized and characterized by elemental analysis, IR spectra and single The crystal belongs to monoclinic, space group P2 / c with a = 0.876 4 (2) nm, b = 1.233 0 (3) nm, c = 1.761 2 (4) nm, β = 109.152 The final R = 0.043 (9) °, V = 1.797 8 (7) nm3, Z = 4, Mr = 490.73, Dc = 1.813 g · cm -3, F (000) = 976, μ = 1.258 mm-1 8 and wR = 0.098 9 for 2 880 observed reflections with I> 2σ (I). The structural analysis shows that the complex has a one-dimensional chain structure. CCDC: 609770.