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At room temperature, the reducing reaction between the bis(diphenylphosphino)butane (dppb) ligand and the compound (tfac=2-thenoyltrifluoroacetone) gave luminescent copper complex [Cu(dppb)(tfac)]2. They have been characterized by physicochemical and spectroscopic methods. Crystal structure of the title complex shows that 2-thenoyltrifluoroacetone behaves as chelating ligand and dppb coordinates as bridging bidentate ligand to Cu atoms in the newly prepared copper complex. The crystal is monoclinic, space group P21/n, with cell parameters a = 1.031 0(2) nm, b = 1.873 0(4) nm, c = 1.763 0(4) nm, β = 95.10(3)°, Z = 4, V = 3.391 0(12) nm3, R = 0.060 3, wR = 0.143 4. CCDC: 228393.
At room temperature, the reducing reaction between the bis (diphenylphosphino) butane (dppb) ligand and the compound (tfac = 2-thenoyltrifluoroacetone) gave luminescent copper complex [Cu (dppb) (tfac)] 2. They have been characterized by physicochemical and spectroscopic methods. Crystal structure of the title complex shows that 2-thenoyltrifluoroacetone behaves as chelating ligand and dppb coordinates as bridging bidentate ligand to Cu atoms in the newly prepared copper complex. The crystal is monoclinic, space group P21 / n, with cell parameters a = 1.031 0 (2) nm, b = 1.873 0 (4) nm, c = 1.763 0 (4) nm, β = 95.10 (3) °, Z = 4, V = 3.391 0 3, wR = 0.143 4. CCDC: 228393.