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本文研究了氧化三甲胺Ｍｅ３ＮＯ与羰基簇合物Ｍ４（ＣＯ）１２－ｎＬｎ（Ｍ＝Ｃｏ，Ｉｒ；ｎ＝１，２；Ｌ＝磷配体）的氧转移反应动力学，讨论了反应机理．反应符合二级速率方程：ｒ＝的氧转移反应活性呈现如下顺序：中心元素不同时取代配体不同时Ｍ４取代程度不同时本文重点讨论了配合物的结构因素对氧转移反应活性的影响．
In this paper, the kinetics of oxygen transfer reaction between trimethylamine oxide Me3NO and carbonyl clusters M4 (CO) 12-nLn (M = Co, Ir; n = 1,2; L = phosphorus ligands) was studied and the reaction mechanism was discussed. The reaction is in accordance with the second-order rate equation: The oxygen transfer activity of r = is in the following order: the central element does not simultaneously replace the ligand and the degree of M4 substitution is different at the same time. This article focuses on the structural factors of the complex on the oxygen transfer reaction activity.