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The reaction between [Cu2(m-dppm)2(MeCN)4](ClO4)2(dppm = bis(diphenylphos- phino)methane) and [Zn(PhS)2(bpy)] (bpy = 2,2-bipyridine, PhS = benzenethiolate) gave the complex [Cu2(m-dppm)2(m-PhS)(MeCN)]ClO40.5(Et2O)(C58H52ClNO4P4SCu20.5Et2O) which was determined by X-ray single-crystal diffraction. The crystal is of orthorhombic, space group P212121 with a = 13.6157(3), b = 20.8022(6), c = 21.3299(6) ? V = 6041.4(3) 3, Mr = 1182.54, Dc = 1.300 g/cm3, F(000) = 2444, m = 0.934 mm-1 and Z = 4. The final R = 0.0773 and wR = 0.1843 for 7744 observed reflections (I > 2s(I)). The dicopper atoms are doubly bridged by dppm as well as one S donor from benzenethiolate. One copper atom is in a distorted trigonal bipyramidal environ- ment, whereas the other adopts a distorted tetrahedral geometry.
The reaction between [Cu2 (m-dppm) 2 (MeCN) 4] (ClO4) 2 (dppm = bis (diphenylphos- phino) methane) and [Zn (PhS) 2 Which was determined by X-ray single-crystal diffraction. The crystal (Cu2 (m-dppm) 2 (m-PhS) (MeCN)] ClO40.5 (Et2O) (C58H52ClNO4P4SCu20.5Et2O) is of orthorhombic, space group P212121 with a = 13.6157 (3), b = 20.8022 (6), c = 21.3299 (6)? V = 6041.4 (3) 3, Mr = 1182.54, Dc = 1.300 g / 000) = 2444, m = 0.934 mm-1 and Z = 4. The final R = 0.0773 and wR = 0.1843 for 7744 observed reflections (I> 2s (I)). The dicopper atoms are doubly bridged by dppm as well as one S donor from benzenethiolate. One copper atom is in a distorted trigonal bipyramidal environ- ment, and the other adopters a distorted tetrahedral geometry.