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1 引 言银的化学发光分析有光泽精 H2 O2 体系 ,鲁米诺 K2 S2 O8体系等。用AgR+ 络合物 ,在非离子表面活性剂TritonX 30 5存在下 ,催化鲁米诺 H2 O2 体系产生化学发光强度比单独金属银离子产生的化学发光强度高 5倍以上。最低检出限为2 7× 10 -7g/L
1 Introduction Silver chemiluminescence analysis Glossy H2O2 system, Luminol K2 S2 O8 system. In the presence of non-ionic surfactant TritonX 30 5, the chemiluminescence intensity of the luminol H 2 O 2 system catalyzed by AgR + complex was more than 5 times higher than that of the metal silver ion alone. The minimum detection limit of 2 7 × 10 -7g / L