A one-dimensional fluid/Monte-Carlo(MC)hybrid model is developed to describe capacitively coupled SiH_4/Ar discharge,in which the lower electrode is applied by a RF source and pulse modulated by a square-wave,to investigate the modulation effects of the pulse duty cycle on the discharge mechanism.An electron Monte Carlo simulation is used to calculate the electron energy distribution as a function of position and time phase.Rate coefficients in chemical reactions can then be obtained and transferred to the fluid model for the calculation of electron temperature and densities of different species,such as electrons,ions,and radicals.The simulation results show that,the electron energy distribution f(ε)is modulated evidently within a pulse cycle,with its tail extending to higher energies during the power-on period,while shrinking back promptly in the afterglow period.Thus,the rate coefficients could be controlled during the discharge,resulting in modulation of the species composition on the substrate compared with continuous excitation.Meanwhile,more negative ions,like Si H_3~-and Si H_2~-,may escape to the electrodes owing to the collapse of ambipolar electric fields,which is beneficial to films deposition.Pulse modulation is thus expected to provide additional methods to customize the plasma densities and components. A one-dimensional fluid / Monte-Carlo (MC) hybrid model is developed to describe capacitively coupled SiH_4 / Ar discharge, where the lower electrode is applied by a RF source and pulse modulated by a square-wave, to investigate the modulation effects of the pulse duty cycle on the discharge mechanism. An electron electron Monte Carlo simulation is used to calculate the electron energy distribution as a function of position and time phase. Rapid coefficients in chemical reactions can then be obtained and transferred to the fluid model for the calculation of electron temperature and densities of different species, such as electrons, ions, and radicals. The simulation results show that, the electron energy distribution f (ε) is modulated evidently within a pulse cycle, with its tail extending to higher energies during the power -on period, while shrinking back promptly in the afterglow period.Thus, the rate coefficients could be controlled during the discharge, resulting in modulation of the species composition on the substrate is compared with continuous excitation. However, more negative ions, like Si H 3 ~ -and Si H 2 ~, may escape to the electrodes due to the collapse of ambipolar electric fields, which are beneficial to film deposition. to provide additional methods to customize the plasma densities and components.