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用MNDO方法研究了1,1-二氯双硅烷的热分解反应,得到了两条反应途径及其过渡态,证明了1,1-二氯双硅烷的热分解是通过1,2-氢迁移和2,1-氢迁移实现的。
The thermal decomposition of 1,1-dichlorobisilane was studied by MNDO method. Two reaction routes and transition states were obtained. It was proved that thermal decomposition of 1,1-dichlorobisilane was achieved by 1,2-hydrogen migration And 2,1-hydrogen migration.