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A ternary adduct Cu[S2P(OCH2CH2Ph)2]2·bipy(bipy=α,α’-bipyridine) was syn-thesized and characterized by elemental analysis,IR and single-crystal X-ray diffraction.The crystal belongs to the triclinic system,space group P1 with a=10.2320(2),b=11.5249(3),c=18.0916(3),α=98.95(1),β =103.601(1),γ=91.272(2)°,V=2044.49(7)3,Z=2,Dc=1.453 g/cm3,T=153(2) K,C42H44CuN2O4P2S4,Mr=894.51,λ(MoKα)=0.71073,μ=0.86 mm-1,S=0.999,(△/σ)max=0.002,the final R=0.0243 and wR=0.0704.A total of 9221 unique reflections were collected,of which 8573 with Ⅰ > 2σ(Ⅰ) were observed.The Cu(Ⅱ) atom is five-coordinated in a rather distorted trigonal bipyramidal geometry(τ value=0.537).The Cu-S distances range from 2.3491(4) to 2.4829(4) ,and the Cu-N distances are 1.9987(12) and 2.0584(11) ,respectively.An interesting feature of this adduct resides in its two-dimensional(2D) open framework constructing through hydrogen bonding and π-π interactions.
A synuclein adduct Cu [S2P (OCH2CH2Ph) 2] 2 · bipy (bipy = α, α’-bipyridine) was syn-thesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal belongs to the triclinic a = 98.95 (1), β = 103.601 (1), γ = 91.272 (2) °, space group P1 with a = 10.2320 2, b = 11.5249 3, c = 18.0916 3, V = 2044.49 (7) 3 Z = 2 Dc = 1.453 g / cm3 T = 153 (2) K C42H44CuN2O4P2S4 Mr = 894.51 λ (MoKα) = 0.71073 μ = 0.86 mm-1 S = 0.999, (Δ / σ) max = 0.002, the final R = 0.0243 and wR = 0.0704.A total of 9221 unique reflections were collected, of which 8573 with I> 2σ (Ⅰ) were observed.The Cu (II) atom and Cu-N distances are 1.9987 (12) and 2.0584 (2) are five-coordinated in a rather distorted trigonal bipyramidal geometry (τ value = 0.537). The Cu-S distances range from 2.3491 (4) to 2.4829 11) , respectively. An interesting feature of this adduct resides in its two-dimensional (2D) open framework constructing through hydrogen bonding and π-π interactions.