It is noted that the rescattering and annihilation effects are significant in the penguin-dominant B→VV decays. In this work, we suggest to use a unique operator at the quark level to describe all the rescattering and the penguin-induced annihilation effects in B→φK*, and the coefficient of the operator depends on the polarizations of the produced mesons. By the flavour SU(3) symmetry, we apply the same scenario to all the penguin-dominant B→VV modes.