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A new three-dimensional coordination polymer [Mn(2,3-pdc)(H2O)]n (2,3-pdc=pyridine-2,3-dicarboxylate) 1 has been hydrothermally synthesized and structurally characterized. The crystal belongs to the monoclinic system,space group P21/c with a=6.4168(5),b=10.7939(9),c=11.1549(10),β=94.733(4)o,V=769.98(11)3,Z=4,Mr=238.06,Dc=2.054 g/cm3,μ(MoKα)=1.707 mm-1,F(000)=476,Rint=0.0326,R=0.0499 and wR=0.1636 for 1564 observed reflections with I > 2σ(I). X-ray diffraction analyses reveal that the title compound is a three-dimensional coordination polymer consisting of one MnII center with a distorted octahedral environment arranged by four 2,3-pdc ligands and one water molecule.
A new three-dimensional coordination polymer [Mn (2,3-pdc) (H2O)] n (2,3-pdc = pyridine- 2,3-dicarboxylate) 1 has been hydrothermally synthesized and structurally characterized. The crystal belongs to the (11) 3, Z = 1, (2) lin, = monoc monoc monoc space space space space space space space space monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc monoc = 4 = Mr = 238.06, Dc = 2.054 g / cm3, μ (MoKα) = 1.707 mm-1, F (000) = 476, Rint = 0.0326, R = 0.0499 and wR = 0.1636 for 1564 observed reflections with I> X-ray diffraction analyzes that reveal the title compound is a three-dimensional coordination polymer consisting of one MnII center with a distorted octahedral environment arranged by four 2,3-pdc ligands and one water molecule.