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考察了ＡｌＥｔ_２Ｃｌ／ｔ－ＢｕＣｌ引发体系的α－蒎烯阳离子聚合反应行为。结果表明，ＡＩＥｔ_２Ｃｌ单独不能引发α－蒎烯聚合，与ｔ－ＢｕＣｌ复合后才具有引发活性，其引发活性随ｔ－ＢｕＣｌ／ＡｌＥｔ_２Ｃｌ的不同而变化，质谱分析表明α－蒎烯聚合产物中存在ｔ－ＢｕＣｌ残基（ＣＨ_３）_３Ｃ，证明ｔ－ＢｕＣｌ参与了链的引发反应。进一步实验还表明，ｔ－ＢｕＣｌ与ＡｌＥｔ_２Ｃｌ相互作用除生成活性物质ＢｕＡｌＥｔ_２Ｃｌ_２外，还有烷基化的产物ＡｌＥｔＣｌ_２，ＡｌＣｌ_３生成，聚合反应条件及引发剂加料方式对α－蒎烯转化率及聚合产物组成都有影响。
The α-pinene cationic polymerization of AlEt_2Cl / t-BuCl initiated system was investigated. The results showed that AIEt 2 Cl alone could not induce the polymerization of α-pinene and the complex with t-BuCl. The activity of AIEt_2Cl changed with the change of t-BuCl / AlEt 2 Cl. The results of mass spectrometry showed that there existed t -BuCl residue (CH_3) _3C, t-BuCl involved in the chain initiation reaction. Further experiments also showed that the interaction between t-BuCl and AlEt2Cl, in addition to the formation of the active substance BuAlEt_2Cl_2, the formation of alkylation products AlEtCl_2, AlCl_3, the polymerization conditions and initiator feeding mode on the α-pinene conversion and polymerization product composition Have an impact.