Busting the efficiency of SAPO-34 catalysts for the methanol-to-olefin conversion by post-synthesis

来源 :中国化学工程学报(英文版) | 被引量 : 0次 | 上传用户:BFM_99
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As an effective non-petroleum based process for producing light olefins, the methanol-to-olefin (MTO) route has become an indispensable altative to the industrial production of light olefins. The silicoaluminophosphate SAPO-34 zeolite (CHA-type structure) has proven to be an efficient industrial catalyst for the production of eth-ylene and propylene by the MTO reaction. However, the inherent structure and related diffusion limitations of SAPO-34 limit the mass transport and thus cause rapid deactivation of the catalyst. Fabrication of hierarchical SAPO-34 zeolite is one of the most effective strategies to address the intrinsic diffusion limitation. As simple, in-expensive, and efficient approach, the post-synthetic route has attracted considerable attention and widely used to introduce secondary meso-/macropores into the microporous SAPO-34 material. Significant effort has been dedicated to the development of post-synthesis strategies to prepare hierarchical SAPO-34 zeolite, thereby en-hancing its catalytic performance in the MTO process. This mini-review addresses the post-synthesis preparation of hierarchical SAPO-34 catalysts and their MTO performance. Furthermore, some current problems and pros-pects of the post-synthesis route to hierarchical SAPO-34 catalysts are also revised. We expect this mini-review to inspire the more efficient preparation of hierarchical SAPO-34 catalysts for the MTO process.
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