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作为多金属氧酸盐材料的重要分支,Strandberg型多金属氧酸盐(例如,[P_2Mo_5O_(23)]~(6-))近些年来由于其独特的与催化、药物、电化学、磁学、荧光相关的结构和性质引起了化学家的广泛关注.Strandberg型多金属氧酸盐有相对小的尺寸,这可能形成不同的架构和稳定的团簇,除了六氧化钼八面体,突出的{PO_4}部分仍然和金属-有机部分配位,这使得它易于构建有机-无机复合材料.本文对Strandberg型多酸的结构特征、合成方法、一系列重要应用和在该领域的应用前景进行了综合的概述.
Strandberg-type polyoxometallates (for example, [P 2 MoO 5O 23 (23)] (6-), as an important branch of polyoxometallate materials, have been used in recent years due to their unique catalytic and pharmaceutical properties, electrochemistry, , Fluorescence-related structures and properties have attracted the attention of chemists.Strandberg-type polyoxometallates have a relatively small size, which may form different architectures and stable clusters except the molybdenum disulfide octahedra, the prominent { PO_4} is still coordinated with the metal-organic moiety, which makes it easy to construct organic-inorganic composites.In this paper, the structural characteristics, synthesis methods, a series of important applications and prospects in the field of Strandberg polyacids are summarized In summary.