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Angew.Chem.Int.Ed.2015,54,1621~1624Rauhut-Currier反应是一个高效构筑碳碳键的基础反应,具有高原子经济性、产物含多种官能团的优点.该反应被发现半个多世纪以来,不同烯烃的交叉Rauhut-Currier反应没有选择性,催化剂用量大,反应底物范围不广的局限性一直没有解决.最近,南开大学元素有机化学国家重点实验室黄有课题组针对Rauhut-Currier反应的缺点,设计了
Angew.Chem.Int.Ed.2015,54,1621 ~ 1624Rauhut-Currier reaction is a basic reaction to efficiently construct carbon-carbon bonds with the advantages of high atom economy and multiple functional groups in the product. The reaction was found to be more than half Over the centuries, the cross-Rauhut-Currier reaction of different olefins has no selectivity, the catalyst dosage is large, the scope of the reaction substrate is not widely the limitations have not been solved.Recently, Nankai University State Key Laboratory of elemental organic yellow research group targeting Rauhut- Currier response to the shortcomings of the design