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有机溶性乙酰丙酮-四-苯基卟啉希土配合物已有报告,但苯基上取代的钇的配合物的衍生物至今没见报道。本文首次制得乙酰丙酮-5,10,15,20-四邻氯苯基卟啉钇Y(o-Cl)Tppacac(H_2Tpp:四苯基卟啉:Hacac:乙酰丙酮;R_1:Cl,R_2=R_3:H),四间氯苯基卟啉钇Y(m-Cl)Tppacac(R_2:Cl,R_1=R_3:H),四对氯苯基卟啉钇Y(p-Cl)Tppacac(R_3:Cl,R_1=R_2:H),四邻甲氧基苯基卟啉钇Y(o-CH_3O)Tppacac(R_1:CH_3O,R_2=R_3:H)和四对甲氧苯基卟啉钇Y(p-CH_3O)Tppacac(R_3:CH_3O,R_1=R_2:H),并用元素分析、红外光谱、紫外光谱和热分析进行了表征。
Organic soluble acetylacetone-tetrakis-phenylporphyrin and its derivatives have been reported, but no derivatives of phenyl-substituted yttrium complexes have been reported so far. In this paper, we first prepared yttrium acetylacetonate-5,10,15,20-tetrachlorophenyl porphyrin Y (o-Cl) Tppacac (H_2Tpp: tetraphenylporphyrin: Hacac: acetylacetone; R_1: Cl, R_2 = R_3 (P-Cl) Tppacac (R_3: Cl) with four chloroporphyrins Y (m-Cl) Tppacac , R_1 = R_2: H), yttrium ortho-o-methoxyphenyl porphyrin Y (o-CH_3O) Tppacac (R_1: CH_3O, R_2 = R_3: H) and yttrium p- ) Tppacac (R_3: CH_3O, R_1 = R_2: H) were synthesized and characterized by elemental analysis, IR, UV and thermal analysis.