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前曾报导N-(间位取代苯基)氨基乙酸,α,α’-联吡啶与铜(Ⅱ),镍(Ⅱ)和锌(Ⅱ),N-(对位取代苯基)氨基乙酸,邻菲啰啉与铜(Ⅱ),镍(Ⅱ),锌Ⅱ)和钴(Ⅱ)生成的三元配合物的稳定性与配体酸碱强度之间的直线自由能关系,本文报导在25℃,0.1mol·dm~(-3)NaClO_4条件下,以邻菲啰啉(phen)为第一配体(A配体),以N-(间位苯取代基)氨基乙酸(简写为m-RPhG,R=CH_3,H,CH_3O,Cl)为第二配体(B配体)与镍(Ⅱ),锌(Ⅱ),钴(Ⅱ),以及α,α’-联吡啶(bipy)为第一配体,以m-RPhG为第二配体与钴(Ⅱ)以及在25℃,0.1mol·dm~(-3)
It has previously been reported that N- (meta-substituted phenyl) glycine, α, α’-bipyridine and copper (II), nickel (II) and zinc (II) The relationship between the stability of ternary complex formed by 1,10-phenanthroline and copper (Ⅱ), nickel (Ⅱ), zinc Ⅱ) and cobalt (Ⅱ) and the linear free energy of the ligand acid- (Meta-benzene substituent) aminoacetic acid (abbreviated as m) with phenanthroline as the first ligand (A ligand) under the conditions of 0.1 mol · dm -3 ℃ and 0.1 mol · dm -3 NaClO 4, (B ligands) and nickel (II), zinc (II), cobalt (II), and α, α’-bipyridyl groups As the first ligand, m-RPhG as the second ligand and cobalt (Ⅱ) and at 25 ℃, 0.1mol · dm ~ (-3)