Utilizing Si, Fe and Mn concentrations within the end-member PACMANUS hydrothermal fluid, Si-Fe-MnH_2 O Pourbaix diagrams were constructed at 300°C and 25°C. The Pourbaix diagrams show that the main Si, Fe and Mn oxides species precipitating from the hydrothermal fluid were Si O_2, Fe(OH)_3, Fe_3(OH)_8, Mn_3O_4, and Mn_2O_3 at 25°C. During mixing of hydrothermal fluid with seawater, Si O_2 precipitated earlier than FeMn-oxyhydroxides because of the lower stability boundary. Then Fe(OH)_2 precipitated first, followed by Fe_3(OH)_8 and Fe(OH)_3, and last, small amounts of Mn_3O_4 and Mn_2O_3 precipitated. Fe(OH)_3 was readily deposited in alkaline solution with little influence by Eh. There were many Si-Fe-Mn-concentric particles in the polished sections of the massive precipitates collected from PACMANUS. In the concentric nucleus and ellipsoid, Si oxides precipitated first before the hydrothermal fluid had mixed with seawater. In the concentric nucleus, after the precipitation of Si oxides, the increase of p H and Eh promoted the precipitation of Mn oxides around the Si oxides. In the large ellipsoid, the precipitation of Fe was divided into two periods. In the early period, increase of p H value of hydrothermal fluid produced by low-temperature convection and an input of a small volume of seawater promoted a small amount of Fe(OH)_3 to precipitate in the Si-rich core. In the late period, after complete mixing with seawater and the resultant fluid was close to neutral or slightly alkaline in p H, Fe(OH)_3 was easily precipitated from the solution and distributed around the Si-rich core. Utilizing Si, Fe and Mn concentrations within the end-member PACMANUS hydrothermal fluid, Si-Fe-MnH 2 O Pourbaix diagrams were fabricated at 300 ° C and 25 ° C. The Pourbaix diagrams show that the main Si, Fe and Mn oxides species precipitating from the hydrothermal fluid were SiO_2, Fe (OH) _3, Fe_3 (OH) _8, Mn_3O_4, and Mn_2O_3 at 25 ° C. During mixing of hydrothermal fluid with seawater, Si O_2 precipitated earlier than FeMn-oxyhydroxides due to the lower stability Then Fe (OH) _2 precipitated first, followed by Fe_3 (OH) _8 and Fe (OH) _3, and last, small amounts of Mn_3O_4 and Mn_2O_3 precipitated. by Eh. There were many Si-Fe-Mn-concentric particles in the polished sections of the massive precipitates collected from PACMANUS. In the concentric nucleus and ellipsoid, Si precipitated first before the hydrothermal fluid had mixed with seawater. In the concentric nucleus , after the precipitation of Si oxides, the increase of p H and Eh promoted the precipitation of Mn oxides around the Si oxides. In the large ellipsoid, the precipitation of Fe was divided into two periods. In the early period, increase of p H value of hydrothermal fluid produced by low-temperature convection and an input of a small volume of seawater promoted a small amount of Fe (OH) _3 to precipitate in the Si-rich core. In the late period, after complete mixing with seawater and the resultant fluid was close to neutral or slightly alkaline in p H, Fe (OH) _3 was easily precipitated from the solution and distributed around the Si-rich core.