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将邻菲罗啉和过量的FeCl2 在DMF、甲醇及异丙醇混合溶剂中直接反应 ,最后得到标题化合物———黑色柱状晶体 ,它具有荧光性能 ,不溶于乙醚 ,可溶于水、DMF、乙醇等极性溶剂 .X -射线结晶学研究结果表明 :标题化合物中含有 [Fe(phen) 3 ]2 + 和 [(μ -oxo)Fe2 Cl6]2 -络合离子以及一个DMF分子 ,晶胞参数 :P 2 1/c ,Z =4,a=1.5 491(1)nm ,b=1.32 18(4 )nm ,c=2 .0 748(2 )nm ,β=93.83° ,V=4.2 387(15 )nm3 ,Dc=1.5 6 2g/cm3 ,μ(MoKα) =1.433mm-1,F(0 0 0 ) =2 0 16 .化学实验式为 :C3 9H3 1Cl6Fe3 N7O2 .分子量 Mr=10 0 9.96 .对标题物进行红外、紫外、可见和荧光光谱及磁化率的测定
The phenanthroline and excess FeCl2 in DMF, methanol and isopropanol mixed solvent direct reaction, and finally the title compound --- black columnar crystals, it has the fluorescence properties, insoluble in ether, soluble in water, DMF, Ethanol and other polar solvents.X - ray crystallography results show that the title compound contains [Fe (phen) 3] 2 + and [(μ -oxo) Fe2 Cl6] 2 - complex ions and one DMF molecule, Parameters: P 2 1 / c, Z = 4, a = 1.5 491 (1) nm, b = 1.32 18 (4) nm, c = 2.0748 (2) nm, β = 93.83 °, V = 4.2 387 (15) nm3, Dc = 1.56 2g / cm3, μ (MoKα) = 1.433mm-1, F (0 0 0) = 2 0 16. The chemical formula is: C3 9H3 1Cl6Fe3 N7O2. Molecular weight Mr = 10 0 9.96 Title, infrared, ultraviolet, visible and fluorescence spectra and susceptibility measurements