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本文利用1.6——二溴己烷将Schiff碱镍金属配合物和吡啶杂环分子联接起来,合成了一类新的六亚甲基桥链化合物(LNi[O(CH_2)_6Py]Br_2),并进行了表征和一些性能研究.这类桥链化合物具有良好的脂溶性,从而提高了这类Schiff碱金属配合物在有机溶剂中的溶解性,为进一步研究这类金属配合物的反应提供了一个好的方法.
In this paper, a new type of hexamethylene bridged compound (LNi [O (CH_2) _6Py] Br_2) was synthesized by coupling Schiff base nickel metal complexes and pyridine heterocyclic molecules with 1.6-dibromohexane Has been characterized and some properties of these bridged compounds have good lipid solubility, thereby increasing the solubility of these Schiff base metal complexes in organic solvents, to further study the reaction of such metal complexes provide a Good method.