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利用分子自组装方法合成了一种新奇的一维链状桥联双核铜配合物,用元素分析,红外光谱,电子光谱,摩尔电导,x 射线四圆衍射等方法对其结构进行了表征,配合物分子中含两个铜( I I)离子,金属离子之间通过 4,4′联吡啶桥连起来,每个铜( I I)离子处于由 5 个氮原子组成的 D3h 对称性的三角双锥配位环境中。
A novel one-dimensional chain-bridged binuclear copper complex was synthesized by molecular self-assembly method. Its structure was characterized by elemental analysis, infrared spectroscopy, electron spectroscopy, molar conductance and x-ray diffraction. The complex contains two copper (II) ions. The metal ions are bridged by 4,4’-bipyridyl and each of the copper (I I) ions is in the D3h symmetry of five nitrogen atoms Triangle bipyramid coordination environment.