A Facile Stereospecific Synthesis of 1, 3-Enynylsulfides via Sonogashira Coupling of (E)-α-Iodovinyl

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：drygps

【摘要】

：

(E)-α-Iodovinyl sulfides 1 underwent the Sonogashira coupling reactions with terminal alkynes 2 in piperidine at room temperature in the presence of 5 mol % of

【作者】

：

Jian Wen JIANG Ming Zhong CAI

【机构】

：

Department of Chemistry

【出处】

：

中国化学快报（英文版）

【发表日期】

：

2004年期

【关键词】

：

(E)-α-Iodovinyl sulfide 1 3-enynylsulfide Sonogashira coupling terminal alkyne

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(E)-α-Iodovinyl sulfides 1 underwent the Sonogashira coupling reactions with terminal alkynes 2 in piperidine at room temperature in the presence of 5 mol % of Pd(PPh3)4 and 10 mol %of CuI to afford the corresponding 1, 3-enynylsulfides 3 stereospecifically in high yields.

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A Facile Stereospecific Synthesis of 1, 3-Enynylsulfides via Sonogashira Coupling of (E)-α-Iodovinyl

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