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报道了6个新的含均同或混合茂铁阳离子和[M(dmit)_2]阴离子的金属有机自由基离子盐类化合物[Fe(CpMe)_2]IM(dmit)_2]和[FeCp(Tol)],[M(dmit)_2]的合成和鉴定,测定了化合物的电导率,讨论了化合物的结构对电导率的影响,发现[Fe(CpMe)_2][M(dmit)_2]的室温电导率比相应的[M(mnt)_2]阴离子盐要高3～7个数量级.
Six novel metal-organic free-radical ionic compounds [Fe (CpMe) _2] IM (dmit) _2] and [FeCp (Tol) with uniform or mixed ferrocene cations and [M )], [M (dmit) _2] were synthesized and characterized. The conductivity of the compounds was measured. The influence of the structure of the compounds on the conductivity was discussed. Conductivity than the corresponding [M (mnt) _2] anion salt is 3 to 7 orders of magnitude higher.