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A new compound [Zn3(C7NO4H3)3Cl4]·[C6NO2H6]4·4H2O (I) has been synthesized and structurally characterized by X-ray crystallography.It crystallizes in monoclinic,space group C2/c with a=16.9018(14),b=12.6902(10),c=25.1170(2),β=90.54°,V=5387.0(8)3,Z=4,Zn3C45H41Cl4N7O24,Mr=1401.76,Dc=1.728 g/cm3,F(000)=2840,μ(MoKa)=1.615 mm-1,the R= 0.0758 and wR=0.2060 for 3468 observed reflections (I > 2σ(I)).Analysis of single-crystal X-ray diffraction data shows that compound I displays an interesting example of 3D supramolecular networks with perfect neutral and ionic hydrogen bonding array.
A new compound [Zn3 (C7NO4H3) 3Cl4] [C6NO2H6] 4H42O (I) has been synthesized and structurally characterized by X-ray crystallography. It crystallizes in monoclinic space group C2 / c with a = 16.9018 b = 12.6902 (10), c = 25.1170 (2) , β = 90.54 °, V = 5387.0 (8) 3, Z = 4 and Zn3C45H41Cl4N7O24, Mr = 1401.76 and Dc = 1.728 g / = 2840, μ (MoKa) = 1.615 mm-1, the R = 0.0758 and wR = 0.2060 for 3468 observed reflections (I> 2σ (I)). Analysis of single-crystal X-ray diffraction data shows that compound I display an interesting example of 3D supramolecular networks with perfect neutral and ionic hydrogen bonding array.