,Spin-glass state and ferromagnetic order in Cu(Ⅱ)-Fe(Ⅲ) cyanides

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The static and dynamic magnetic properties of a Prussian blue analogue, molecular magnet Cu3Ⅱ[FeⅢ(CN)6]2.3NH3. 6H2O were investigated in detail. The H dependence of the linear AC susceptibility, the irreversibility in the field-cooled (FC) / zero-field-cooled (ZFC) magnetization (MFc/MzFc) and the relaxation of MZFC suggest that the magnetic system can be visualized as containing a ferromagnetic cluster of spin below TC, mixed with small spinglass clusters formed below temperature Tg less than TC. The observed magnetic properties are explained with a ferromagnetic-spin-glass phase model. The magnetic ordering of the sample occurs below 19.8K.
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