New Process for Preparation Alumina and Silica White from Coal Fly Ash

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Fly ash was used to prepare alumina and silica white, The 3 stages of the process are as follows: ammonium sulfate calcining, acid leaching and alkali dissolution. The optimum conditions for the experiments to determine are as follows: molar ratio of (NH4)2SO4/Al2O3 is 6, the calcining time is 2h, he H2SO4 concentration is 20%, the leaching temperature is 80℃ and dissolution duration is 2h, the ratio of solution and solid reaction material is 6 for ammonium sulfate calcining and acid leaching stage, reaction time 30min, ratio of liquid to ore 5∶1, alkali concentration 45% and reaction temperature 95 ℃for the alkali dissolution stage. Under these conditions, the total leaching efficiencies of Al2O3 and SiO2 are 78.86% and 95%, respectively. The quality of the main products alumina and silica white can meet the national standards of GB/T24487-2009 and GB10517-89, respectively. The optimum conditions for the experiments are determined as follows: molar ratio of (NH4) 2SO4 / Al2O3 is 6, the calcining time is 2h, the H2SO4 concentration is 20%, the leaching temperature is 80 ℃ and the dissolution duration is 2h, the ratio of solution and solid reaction material is 6 for ammonium sulfate calcining and acid leaching stage, reaction time 30min, ratio of liquid to ore 5: 1, alkali concentration 45% and reaction temperature 95 ° C for the alkali dissolution stage. Under these conditions, the total leaching efficiencies of Al2O3 and SiO2 are 78.86% and 95%, respectively. The quality of the main products alumina and silica white can meet the national standards of GB / T24487-2009 and GB10517-89, respectively.
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