本工作从L-谷氨酸和苯乙烯出发合成了单体配位体(S)-2-(对乙烯基苯胺甲基)吡咯烷、以及线性均聚物、线性共聚物和交联共聚物配位体,并以此与LiAlH_4结合形成高分子试剂,以与低分子手性试剂相对比的方法对苯乙酮的不对称还原反应进行了不同配比、温度、溶剂条件下的初步研究,结果表明,高分子试剂在苯乙酮不对称还 In this work, monomeric ligands (S) -2- (p-vinylanilinomethyl) pyrrolidine were synthesized from L-glutamic acid and styrene, and linear homopolymers, linear copolymers and crosslinked copolymers Ligand and thus with LiAlH_4 combined to form a high molecular weight reagent, compared with the low molecular weight chiral reagent asymmetric reduction of acetophenone under different ratio, temperature, solvent under the conditions of the preliminary study, The results show that the polymeric reagent is also asymmetric in acetophenone