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探针原子化法是一种新技术。本文系统地总结了用探针原子化法研究Au(ⅠB),Sr(ⅡA),Cd(ⅡB),Al(ⅢA),La,Sm,Eu(ⅢB),Ge,Sn,Pb(ⅣA),Sb,Bi(ⅤA),V(ⅤB),Cr,Mo(ⅥB),Mn(ⅦB),Fe,Co,Ni,Pt(Ⅷ)等20个元素的原子化机理。原子化起源于卤化物分解的元素有An与Pt,起源于氧化物分解的元素有Cd,Al,La,Sm,Eu,Ge,Mn与Fe,起源碳化物分解的元素有Sr,V,Cr与Mo,起源于氧化物被碳还原的元素有Ph,Co与Ni;其原子化既可起源于卤化物分解又可起源于氧化物分解的元素有Sb;其原子化既可起源于氧化物分解又可起源于氧化物被碳还原的元素有Sn与Bi。对文献与我们实验结果不一致之处作了必要的说明。
Probe atomization is a new technique. In this paper, we systematically summarize the recent progress of probe atomization in Au (ⅠB), Sr (ⅡA), Cd (ⅡB), Al (ⅢA), La, Sm, Eu The atomization mechanism of 20 elements including Sb, Bi (ⅤA), V (ⅤB), Cr, Mo (ⅥB), Mn (ⅦB), Fe, Co, Ni and Pt (Ⅷ) Atomization originates from decomposition of halides by An and Pt, elements that originate from decomposition of oxides with Cd, Al, La, Sm, Eu, Ge, Mn and Fe, and decomposition of starting carbides with Sr, V, Cr And Mo, originated from the oxides of carbon-reduced elements Ph, Co and Ni; its atomization can originate in the decomposition of halides can also be derived from the decomposition of oxides of Sb; its atomization can originate from the oxide Decomposition can originate in the oxide is carbon-reduced elements Sn and Bi. Necessary explanations are provided for the inconsistencies between the literature and our experimental results.