我国目前积存一定数量的遗留高放废物(LegacyHLW)亟待处理,其特征之一是钠含量高(Na2O,质量分数为40%～45%,下同),限制了固化基材对废物包容量。本实验将钠的包容量作为研究内容,利用玻璃陶瓷固化工艺制备高钠玻璃陶瓷,其结晶相固定模拟锕系核素。首先设计了不同钠含量的配方,其中,Na2O为10%～30%;结晶相组分CaO、TiO2和ZrO2质量比为(12～13)﹕(9～10)﹕(7～8);Al2O3为7%～27%;SiO2为45%。熔制过程分为熔融、核化 At present, a large amount of Legacy HLW is accumulated urgently in our country. One of its characteristics is that the sodium content is high (Na2O, 40% -45%, the same below), which limits the package capacity of solidified substrate. In this experiment, the capacity of sodium as a research content, the use of glass ceramic curing process for the preparation of high-sodium glass ceramics, the crystalline phase of the fixed simulation actinide nuclides. Firstly, the formula of different sodium content was designed, in which Na2O was 10% ~ 30%; the mass ratio of CaO, TiO2 and ZrO2 was (9 ~ 10) :( 7 ~ 8) 7% ~ 27%; SiO2 45%. Melting process is divided into melting, nuclear