我们在另文报道了以芳香叔胺作酯基的丙烯酸酯单体,甲基丙烯酸4-(N,N-二甲氨基)苄酯(DMABMA)与过氧化月桂酰(LPO)能形成氧化还原体系引发它自身的聚合。我们发现,这种具有芳香叔胺基的丙烯酸酯,亦能作为引发剂引发其它烯类单体的聚合,而其本身也参与聚合而进入聚合物链中,芳香叔胺,如N,N-二甲基对甲苯胺(DMT),N,N-二甲基苯胺(DMA)等在不另加过氧化物存在下,能以自由基机构引发烯类单体的聚合已有若干报 We report in another article that aromatic tertiary amines as ester-based acrylate monomers, 4- (N, N-dimethylamino) benzyl methacrylate (DMABMA) and lauroyl peroxide (LPO) The system triggers its own aggregation. We have found that such aromatic tertiary amino-containing acrylates also act as initiators for the polymerization of other ethylenic monomers and are themselves involved in polymerization into the polymer chain. Aromatic tertiary amines, such as N, N- There have been several reports of DMT, DMA, and the like that can initiate the polymerization of vinyl monomers with free-radical mechanisms without the presence of additional peroxides