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甘薯麦娥 Brachmia triannuella H.S.是为害甘薯的主要害虫之一。甘薯麦蛾的性诱剂于1976年经C.Hiran等研究确定,是反-11-十六碳烯酵醋酸酯。我们在1977年着手合成。合成的方法是从癸二醇开始,经制成溴醇,连以四氢吡喃保护基团,在液氨中连上炔基,与溴丁烷缩合,产物经反式加氢,脱保护基团,再酯化而得反-11-十六碳烯醇醋酸酯:
Sweet potato Mai E Brachmia triannuella H.S. is one of the major pests for sweet potato. Sweet potato moth sex lure in 1976 by C.Hiran other studies to determine, is anti-11-hexadecene fermentate. We started in 1977 synthesized. The synthesis method starts from decane diol and is made into a bromohydrin, which is connected with a tetrahydropyran protecting group, an alkynyl group is connected with the liquid ammonia, condensed with bromobutane, the product is transhydrogenated and deprotected Trans-esterified to give trans-11-hexadecenol acetate: