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本文研究了Ｍｏ￣ⅤＯ（ＴＰＰ）Ｃｌ与Ｏ＿２的反应机理。结果表明，在１：１体积比ＣＨ＿２Ｃｌ＿２－ＤＭＳＯ溶剂中，在１８－ｃｒｏｗｎ－６存在下，配合物Ｍｏ￣ⅤＯ（ＴＰＰ）Ｃｌ被Ｏ￣－＿２还原的反应通过一系列中间物，最后生成Ｍｏ￣ⅣＯ（ＴＰＰ）（１８－ｃｒｏｗｎ－６），本文给出了详细的反应动力学网络。
In this paper, the reaction mechanism of Mo ~ VO (TPP) Cl with O_2 has been studied. The results showed that the reaction of Mo ~ VO (TPP) Cl with O ~ -_2 reduced in a 1: 1 volume ratio CH_2Cl_2-DMSO solvent in the presence of 18-crown-6 through a series of intermediates, ~ Ⅳ O (TPP) (18-crown-6), this paper gives a detailed reaction kinetics network.