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A Cd(Ⅱ)-nitronyl nitroxide radical complex with dicyanoaurate(Ⅰ) bridges [Cd(NIT4Py)2][Au(CN)2]2, was synthesized and characterized by elemental analyses, IR spectrum and X-ray diffraction single-crystal structure analysis. Crystal data for the complex: triclinic, space group P, a=0.720 9(11) nm, b=0.960 3(15) nm, c=1.284(2) nm, α=75.38(2)°, β=85.46(2)°, γ=68.38(2)°, V=0.800(2) nm3, Z=1, and R1 [I>2σ(I)]=0.055 8. The title complex consists of infinite one-dimensional chains of [Cd(NIT4Py)2][Au(CN)2]2, in which [Cd(NIT4Py)2] moieties are conne-cted by [Au(CN)2]- μ2-bridging ligands. Each cadmium(Ⅱ) ion is six-coordinated in a distorted and centrosymmetric octahedral environment. CCDC: 258357.
A Cd (II) -nitronyl nitroxide radical complex with dicyanoaurate (Ⅰ) bridges [Cd (NIT4Py) 2] [Au (CN) 2] 2 was synthesized and characterized by elemental analyzes, IR spectrum and X- a = 0.720 9 (11) nm, b = 0.960 3 (15) nm, c = 1.284 (2) nm, α = 75.38 (2) °, β = 85.46 (2) °, γ = 68.38 (2) °, V = 0.800 (2) nm3, Z = 1 and R1 [I> 2σ (I)] = 0.055 8. The title complex consists of infinite one- dimensional chains of [Cd (NIT4Py) 2] [Au (CN) 2] 2, which [Cd (NIT4Py) 2] moieties are conne- cted by [Au (CN) 2] Ⅱ) ion is six-coordinated in a distorted and centrosymmetric octahedral environment. CCDC: 258357.