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The insertion of CS_2 into M--S bonds has been studied. CS_2 can be inserted intopart of a set of Cu--S or Ag--S bonds in polynuclear compounds, forming clusterswith thiolate (RS~-) and trithiocarbonate (RSCS_2~-) mixed ligands. This is anew way to prepare clusters with sulphur-containing ligands, In 1986, Chadha reportedthe first cluster complex Cu_8(S_2CSMe_2Et)_4(SCMe_2Et)_4 prepared by insertionof CS_2 into Cu--S bonds. In recent years, we have obtained several clusters with
The insertion of CS_2 into M - S bonds has been studied. CS_2 can be inserted intopart of a set of Cu - S or Ag - S bonds in polynuclear compounds, forming clusters with thiolate (RS ~ -) and trithiocarbonate (RSCS_2 ~ -) mixed ligands. This is a new way to prepare clusters with sulfur-containing ligands, In 1986, Chadha reported the first cluster complex Cu_8 (S_2CSMe_2Et) _4 (SCMe_2Et) _4 prepared by insertion of CS_2 into Cu - S bonds. we have obtained several clusters with